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Ethyl 1,3-dithiane-2-carboxylate

Ethyl 1,3-dithiane-2-carboxylate

Catalog Number:
CBB1135566
Mfr. No.:
43749
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  • Size:
    5mL
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      • Overview

        • Ethyl 1,3-dithiane-2-carboxylate is an α-keto acid equivalent and bulky equivalent of acetate. It participates in syn-selective aldol reactions. It can be prepared from the reaction of ethyl diethoxyacetate and 1,3-propanedithiol in the presence of BF3/Et2O. Asymmetric oxidation of ethyl 1,3-dithiane-2-carboxylate by Modena protocol has been reported to afford trans bis-sulfoxide in 60% yield. Carbanion from ethyl 1,3-dithiane-2-carboxylate may be employed for the preparation of α-keto esters.

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      • Properties
        • Alternative Name
          Glyoxylic acid ethyl ester trimethylenemercaptal
          CAS Number
          20462-00-4
          Molecular Formula
          C7H12O2S2
          Molecular Weight
          192.30
          MDL Number
          MFCD00006657
          Others
          SID 24867377
          Hazard Information
          Warning
          Flammable liquids
          Note
          Please note that Amerigo Scientific does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

          * For Research Use Only.

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