Name: Methyl 2-bromoacrylate
Price: 285.00 USD

- Overview
  - Methyl α-bromoacrylate can undergo radical copolymerization with vinyl triacetoxysilane (VTAS) in the presence of azobisisobutyronitrile as the initiator. Dibromocyclopropanation of methyl α-bromoacrylate can yield methyl 1, 1, 2-tribromocyclopropanecarboxylate. It may be reduced with zinc dust and deuterium oxide to synthesize. Methyl acrylate-α-d with a high isotopic purity. These may undergo conjugate addition with methoxide, thiolates, oxime anions, hydrazones and EtZnCl to afford ester enolates.
    
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- Properties
  - Alternative Name
    
    Methyl 2-bromoacrylate | 4519-46-4 | methyl 2-bromoprop-2-enoate | Methyl alpha-bromoacrylate | 2-Propenoic acid, 2-bromo-, methyl ester | MFCD08276754 | METHYL ALPHA-BROMOACRYLATE95 | Methyl | A-bromoacrylate | Methyl2-bromoacrylate | Methyl 2-bromoacrylate # | Methyl alpha
    
    CAS Number
    
    4519-46-4
    
    Molecular Formula
    
    C4H5BrO2
    
    Molecular Weight
    
    164.99
    
    Purity
    
    96% (containing stabilizer MEHQ)
    
    Other Properties
    
    Sensitivity: light sensitive
    Flash Point (°F): 134.6 °F
    Flash Point (°C): 57 °C
    Boil Point (°C): 70-75 °C/48 mmHg
    
    Storage
    
    Protected from light. Store at -20°C
    
    Shipping
    
    Dry ice
    
    SMILES
    
    COC(=O)C(=C)Br
    
    InChi
    
    InChI=1S/C4H5BrO2/c1-3(5)4(6)7-2/h1H2,2H3
    
    InChi Key
    
    HVJXPDPGPORYKY-UHFFFAOYSA-N
    
    PubChem CID
    
    229990
    
    Others
    
    IUPAC Name: methyl 2-bromoprop-2-enoate
    
    Hazard Information
    
    Hazard Statements: H315,H319,H335,H226
    Precautionary Statements: P261,P305+P351+P338
    WGK Germany: 3
    
    * For research use only. Not for use in human or animal.

MSDS

Methyl 2-bromoacrylate

Methyl 2-bromoacrylate

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