Bis(trimethylsilyl)acetylene (99%)

Bis(trimethylsilyl)acetylene (99%)

Catalog Number:
CBB1113655
Mfr. No.:
187437
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      • Overview
        • Bis(trimethylsilyl)acetylene (BTMSA) participates as nucleophile in Friedel-Crafts type acylations and alkylations. BTMSA undergoes rhodium catalyzed addition reaction with diarylacetylenes. It undergoes cycloaddition with 1,5-hexadiynes in the presence of CpCo(CO)2 (Cp=cyclopentadienyl) to form benzocyclobutenes. Structure of BTMSA was characterized by a centre of inversion present on triple bond (length=1. 208(3)Å). TiCl4-Et2AlCl catalyzed Diels-Alder reaction of BTMSA with norbornadiene has been reported.

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      • Properties
        • Categories
          Organic Building Blocks
          Alternative Name
          BTMSA
          CAS Number
          14630-40-1
          Molecular Formula
          (CH3)3SiC≡CSi(CH3)3
          Molecular Weight
          170.40
          Purity
          99%
          Storage
          2-8°C
          SMILES
          C[Si](C)(C)C#C[Si](C)(C)C
          InChi
          1S/C8H18Si2/c1-9(2,3)7-8-10(4,5)6/h1-6H3
          InChi Key
          ZDWYFWIBTZJGOR-UHFFFAOYSA-N
          MDL Number
          MFCD00008276
          Others
          SID 24851275
          Hazard Information
          Danger
          Flammable liquids
          Note
          Please note that Amerigo Scientific does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

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