Name: 6,6-Dimethylfulvene (≥95%)
Price: Inquiry

- Overview
  - 6,6-Dimethylfulvene [5-(1-methylethylidene)-1,3-cyclopentadiene] is a nonaromatic carbocyclic analog of isopropylbenzene. 6,6-Dimethylfulvene reacts with 2,2-bis(trifluoromethyl)-1,1-dicyanoethylene (BTF; 1) to afford the expected Diels-Alder cycloadduct, 7-(1-methylethylidene)-3,3-bis(trifluoromethyl)bicyclo[2. 2. 1]hept-5-ene-2,2-dicarbonitrile. Metal-free hydrogenation of 6,6-dimethylfulvene via frustrated Lewis pair (FLP) mediated triple domino reaction has been reported. The biotransformation of 6,6-dimethylfulvene by Pseudomonas putida RE213 has been studied. Cycloaddition of 6,6-dimethylfulvene with benzynes has been reported. 6,6-Dimethylfulvene undergoes nucleophilic reaction with lithium dichloromethide in the presence of THF at -75°C, selectively at its exocyclic double bond.
    
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- Properties
  - Categories
    
    Organic Building Blocks
    
    Alternative Name
    
    5-Isopropylidene-1,3-cyclopentadiene; 5-(1-Methylethylidene)-1,3-cyclopentadiene
    
    CAS Number
    
    2175-91-9
    
    Molecular Formula
    
    C8H10
    
    Molecular Weight
    
    106.17
    
    Purity
    
    ≥95%
    
    Storage
    
    −20°C
    
    SMILES
    
    C\C(C)=C1/C=CC=C1
    
    InChi
    
    1S/C8H10/c1-7(2)8-5-3-4-6-8/h3-6H,1-2H3
    
    InChi Key
    
    WXACXMWYHXOSIX-UHFFFAOYSA-N
    
    MDL Number
    
    MFCD00011655
    
    Others
    
    SID 57649965
    
    Hazard Information
    
    Danger
    Flammable liquids
    
    Note
    
    Please note that Amerigo Scientific does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.
    
    * For Research Use Only.

6,6-Dimethylfulvene (≥95%)

6,6-Dimethylfulvene (≥95%)

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