4-Ethoxy-1,1,1-trifluoro-3-buten-2-one

4-Ethoxy-1,1,1-trifluoro-3-buten-2-one

Catalog Number:
CBB1116117
Mfr. No.:
407771
Price:
  • Size:
    5g
    Quantity:
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      • Overview
        • 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one reacts with phenylmagnesium bromide to afford ethoxy group substitution products, while it reacts with organozinc compounds to yield products arising from 1,2-addition to the carbonyl group. 4-Ethoxy-1,1,1-trifluoro-3-buten-2-one on heating with triethyl phosphite affords [4+2] cycloaddition product, 2,2,2-triethoxy 2,3-dihydro-3-ethoxy-5-trifluoromethyl-1,2λ5-oxaphospholene, which on hydrolysis affords a 2-oxo-2-hydroxy-2, 3-dihydro-3-hydroxy 5-trifluoromethyl-1,2λ5-oxaphospholen. It reacts with amino to give the N-protected amino acids, which is useful for the peptide synthesis.

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      • Properties
        • Categories
          Organic Building Blocks
          CAS Number
          17129-06-5
          Molecular Formula
          C2H5OCH=CHCOCF3
          Molecular Weight
          168.11
          Storage
          2-8°C
          SMILES
          CCO\C=C\C(=O)C(F)(F)F
          InChi
          1S/C6H7F3O2/c1-2-11-4-3-5(10)6(7,8)9/h3-4H,2H2,1H3/b4-3+
          InChi Key
          YKYIFUROKBDHCY-ONEGZZNKSA-N
          MDL Number
          MFCD00192131
          Others
          SID 24865486
          Hazard Information
          Warning
          Flammable liquids
          Note
          Please note that Amerigo Scientific does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

          * For Research Use Only.

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